Deleting Duplicate data from MySQL database in PHP

I am making an application from data import from excel file. In application user may be import several time or different file may be contains same data. But I always need unique data row from other calculation. So I badly need delete Duplicated row from table after importing data from excel file.
For Solve this problem I found couple of solution on web.

Solution:1 If table contain a primary key
Table :

 
  create table TableName1 (
  ID int(11) NOT NULL AUTO_INCREMENT ,
  CODE varchar(20) , 
  NAME varchar(100) ,
  PRIMARY KEY (ID)
  ) 
  

Data

ID	CODE	NAME
1	A1001	Mahfuz
2	A1002	Lemon
3	A1001	Mahfuz
4	A1002	Lemon
5	A1003	Babu

 <?php
 $conn = mysql_connect("localhost", "mysql_user", "mysql_password");
if (!$conn) {
    echo "Unable to connect to DB: " . mysql_error();
    exit;
}
if (!mysql_select_db("mydbname")) {
    echo "Unable to select mydbname: " . mysql_error();
    exit;
}



$sql = "DELETE FROM TableName1
USING TableName1, TableName1 AS vtable
WHERE vtable.id > TableName1.id
AND TableName1.CODE = vtable.CODE
And TableName1.NAME = vtable.NAME";

mysql_query($sql);

$sql_check = "SELECT NAME,
COUNT(NAME) AS NumOccurrences
FROM TableName1
GROUP BY NAME
HAVING ( COUNT(NAME) > 1 )";
$result = mysql_query($sql_check);

if (mysql_num_rows($result) == 0) {
    echo "No Duplicate rows found";
}
?>

Solution 2: If table have no primary key
Table :

 create table TableName1 ( 
  CODE varchar(20) , 
  NAME varchar(100)
)

Data

CODE	NAME
A1001	Mahfuz
A1002	Lemon
A1001	Mahfuz
A1002	Lemon
A1003	Babu

 <?php

$conn = mysql_connect("localhost", "mysql_user", "mysql_password");
if (!$conn) {
    echo "Unable to connect to DB: " . mysql_error();
    exit;
}
if (!mysql_select_db("mydbname")) {
    echo "Unable to select mydbname: " . mysql_error();
    exit;
}



$sql1 = " CREATE TEMPORARY TABLE temp_TableName1 as select * from TableName1 group By code,name";

mysql_query($sql1);

$sql2 = " TRUNCATE TABLE TableName1 ";

mysql_query($sql2);

$sql3 = " INSERT INTO TableName1 SELECT * FROM temp_TableName1 ";

mysql_query($sql3);

$sql_check = "SELECT NAME,
COUNT(NAME) AS NumOccurrences
FROM TableName1
GROUP BY NAME
HAVING ( COUNT(NAME) > 1 )";
$result = mysql_query($sql_check);

if (mysql_num_rows($result) == 0) {
    echo "No Duplicate rows found";
}

?>